An open hollow polyoxovanadate cage based on {Nb(V5)} pentagons with size-selective encapsulation properties

Renbo Fang, Di Zhang, Jing Dong*, Yeqin Feng, Chengpeng Liu, Liaoyuan Yao, Yingnan Chi*, Changwen Hu

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

2 引用 (Scopus)

摘要

An open hollow polyoxovanadate (POV) cage, V14Nb2P8, has been successfully constructed using {Nb(V5)} pentagons as building blocks. The POV cage features a crown-ether-like {V4P4O8} opening that can selectively coordinate with Cs+ ions. Additionally, it has a hollow cavity that acts as a molecular container to accommodate size-appropriate organic molecules.

源语言英语
页(从-至)6182-6185
页数4
期刊Chemical Communications
61
33
DOI
出版状态已出版 - 25 3月 2025

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