摘要
High-Cu-content (Cu-content > 1.3 at.%) nanocrystalline alloys exhibit wide heat-treatment windows and favorable soft magnetic properties due to the presence of pre-existing α-Fe nanocrystals. By fabricating ribbons with varying thicknesses to tailor cooling rates, distinct structural characteristics were achieved in Fe82B16.5Cu1.5 alloy ribbons. Notably, the face-centered cubic (fcc) γ-Fe phase was identified in Fe-based nanocrystalline alloys. The precipitation of the fcc γ-Fe phase originates from a phase-selection mechanism under specific cooling conditions, while its retention in the as-quenched ribbon with a thickness of 27 μm is attributed to kinetic suppression during rapid cooling and the nanoscale stabilization effect. The formation of the fcc γ-Fe phase significantly reduced the saturation flux density (Bs) and increased coercivity (Hc), concurrently destabilizing the residual amorphous matrix. By suppressing the precipitation of the γ-Fe and Fe3B phases through precise control of ribbon thickness and annealing parameters, the alloy ribbon with a thickness of 16 μm achieved an optimal combination of Bs (1.82 T) and Hc (8.3 A/m). These findings on anomalous fcc γ-Fe phase precipitation provide novel insights into metastable phase engineering and offer structural design guidelines for alloys containing pre-existing α-Fe nanocrystals.
源语言 | 英语 |
---|---|
文章编号 | 2867 |
期刊 | Materials |
卷 | 18 |
期 | 12 |
DOI | |
出版状态 | 已出版 - 6月 2025 |
已对外发布 | 是 |